QUANTUM-MECHANICS IN PHASE-SPACE - NEW APPROACHES TO THE CORRESPONDENCE PRINCIPLE

被引:107
作者
TORRESVEGA, G [1 ]
FREDERICK, JH [1 ]
机构
[1] INST POLITECN NACL, CTR INVEST ESTUDIOS AVANZADOS, MEXICO CITY 07000, MEXICO
关键词
D O I
10.1063/1.459225
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present a time evolution equation that provides a novel basis for the treatment of quantum systems in phase space for the investigation of the quantum-classical correspondence. Through the use of a generalized Husimi transform, we obtain a phase space representation of the time-dependent Schrodinger equation directly from the coordinate representation. Such an equation governs the time evolution of densities such as the Husimi density entirely in phase space, without recourse to a coordinate or momentum representation. As an application of the phase-space Schrodinger equation, we compute the eigenfunctions of the harmonic oscillator in phase space, relate these to the Husimi transform of coordinate representation eigenstates, and investigate the coherent state, its time evolution, and classical limit h --> 0) for the probability density generated by this state. Finally, we discuss our results as they relate to the quantum-classical correspondence, and quasiclassical trajectory simulations of quantum dynamics.
引用
收藏
页码:8862 / 8874
页数:13
相关论文
共 56 条
[1]  
[Anonymous], 1962, CLASSICAL ELECTRODYN
[2]  
[Anonymous], 1989, CHAOS INTEGRABILITY
[3]  
Bender Carl, 1999, ADV MATH METHODS SCI, V1
[4]  
BOHM A, 1979, PRINCIPLES QUANTUM M
[5]   A METHOD TO CONSTRAIN VIBRATIONAL-ENERGY IN QUASICLASSICAL TRAJECTORY CALCULATIONS [J].
BOWMAN, JM ;
GAZDY, B ;
SUN, QY .
JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (05) :2859-2862
[6]  
Brodkey RS, 1967, PHENOMENA FLUID MOTI
[7]  
Bunker D.L., 1971, METHODS COMPUTATIONA, V10, P287
[8]   ROTATION VIBRATION INTERACTIONS BETWEEN THE 2 LOWEST FREQUENCY MODES IN FORMALDEHYDE [J].
BURLEIGH, DC ;
MAYRHOFER, RC ;
SIBERT, EL .
JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (12) :7201-7216
[9]   ENHANCEMENT OF INTRAMOLECULAR VIBRATIONAL-ENERGY TRANSFER THROUGH ROTATIONAL COUPLING [J].
CLODIUS, WB ;
SHIRTS, RB .
JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (12) :6224-6231
[10]   SEMI-CLASSICAL GAUSSIAN-BASIS SET METHOD FOR MOLECULAR VIBRATIONAL WAVE-FUNCTIONS [J].
DAVIS, MJ ;
HELLER, EJ .
JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (08) :3383-3395