EFFECT OF THE SOLUTION REFRACTIVE-INDEX ON THE COLOR OF GOLD COLLOIDS

被引:677
作者
UNDERWOOD, S
MULVANEY, P
机构
[1] UNIV MELBOURNE, SCH CHEM, ADV MINERAL PROD RES CTR, PARKVILLE, VIC 3052, AUSTRALIA
[2] ROYAL MELBOURNE INST TECHNOL, DEPT APPL PHYS, MELBOURNE, VIC 3000, AUSTRALIA
关键词
Aqueous gold sols - Colloid coagulation - Mie theory - Polymeric comb stabilizer;
D O I
10.1021/la00022a011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aqueous gold sols with a mean diameter of 16 nm have been transferred into various mixtures of organic solvents with different refractive indices using a polymeric comb stabilizer to prevent colloid coagulation. The sols change color from red to purple depending on the refractive index of the solvent. The optical properties of the sols in the different media are in excellent agreement with the predictions of Mie theory.
引用
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页码:3427 / 3430
页数:4
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