FIRST OBSERVATION OF THE V=3 LEVEL OF THE B-(1)SIGMA(+) RYDBERG STATE OF CO

被引：26

作者：

BAKER, J

TCHANGBRILLET, WUL

JULIENNE, PS

机构：

[1] OBSERV PARIS,MEUDON SECT,DAMAP,F-92195 MEUDON,FRANCE

[2] CNRS,URA 812,F-92195 MEUDON,FRANCE

[3] NIST,DIV MOLEC PHYS,GAITHERSBURG,MD 20899

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 102卷 / 10期

关键词：

D O I：

10.1063/1.468523

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new diffuse vuv band of 12C16O at 92 800 cm -1 has been observed in absorption and assigned to the B-X(3-0) transition. The assignment is based on the excellent agreement found between the observed band and a calculated spectrum of the B-X(3-0) transition, where a previously optimized two channel close-coupling model of the B 1Σ+ -D′ 1Σ+ Rydberg-valence predissociation interaction has been used to calculate the B(υ = 3) state molecular constants, J dependent predissociation widths and the J dependent B-X(3-0) vibronic transition moments. The relative absorption cross-section for this transition has also been calculated. © 1995 American Institute of Physics.

引用

页码：3956 / 3961

页数：6

共 23 条

[1] 1ST OBSERVATION OF THE CO E 1-PI-]B-1-SIGMA+ AND C-1-SIGMA+-]B-1-SIGMA+ BAND SYSTEMS - PREDISSODIATION IN THE E-1-PI(NU=0) LEVEL [J].