PODAND-CATALYZED NUCLEOPHILIC AROMATIC SUBSTITUTIONS OF ANTHRAQUINONES - A NOVEL SYNTHETIC APPROACH AND A MECHANISTIC SUGGESTION FROM SOLID-STATE DATA

被引：24

作者：

LU, TB

YOO, HK

ZHANG, HM

BOTT, S

ATWOOD, JL

ECHEGOYEN, L

GOKEL, GW

机构：

[1] UNIV MIAMI,DEPT CHEM,CORAL GABLES,FL 33124

[2] UNIV ALABAMA,DEPT CHEM,UNIVERSITY,AL 35486

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 08期

关键词：

D O I：

10.1021/jo00295a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Haloanthraquinones undergo facile nucleophilic substitution by aliphatic alcohols only when a catalytic amount of oligo(ethylene glycol) derivative is present; the latter serves as both nucleophile and leaving group in the transformation. © 1990, American Chemical Society. All rights reserved.

引用

页码：2269 / 2270

页数：2

共 9 条

[1] CONTRASTING ONE-CATION AND 2-CATION BINDING BEHAVIOR IN SYN-ANTHRAQUINONE AND ANTI-ANTHRAQUINONE BIBRACCHIAL PODAND (BIP) MONO-ANIONS AND DIANIONS ASSESSED BY CYCLIC VOLTAMMETRY AND ELECTRON-PARAMAGNETIC RESONANCE SPECTROSCOPY [J].