UNIMOLECULAR CHEMISTRY OF THE 4-HEXEN-3-ONE RADICAL CATION

被引：1

作者：

BOUCHOUX, G

DJAZI, F

JAUDON, P

LEFEVRE, O

机构：

[1] DCMR, Ecole Polytechnique, Palaiseau

来源：

RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1990年 / 4卷 / 04期

关键词：

D O I：

10.1002/rcm.1290040410

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Ionized 4‐hexen‐3‐one, fragments by losing CH˙3, CO, C2H4 and C2H˙5. The former process, which is found to dominate dissociations of metastable molecular ions proceeds via the cyclized enol cation CH3ĊHCH2CH2C(OH) = CH+. Use of deuterium labelling and relevant thermochemical data allow the determination of the various reaction mechanisms. Copyright © 1990 Heyden & Son Limited

引用

页码：131 / 134

页数：4

共 24 条

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