FLUOROMETRY;
MASS SPECTROMETRY;
CATECHOLAMINES;
DOPAMINE;
EPINEPHRINE;
NOREPINEPHRINE;
D O I:
10.1016/0003-2670(92)85015-X
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
The fluorescent product formed in the reaction between epinephrine and 1,2-diphenylethylenediamine was determined to be 2-phenyl(4,5-dihydro-4-hydroxy-1-methylpyrrolo) [2,3-f]benzoxazole. The difference in the mechanisms of the reactions of 1,2-diphenylethylenediamine and ethylenediamine with epinephrine is discussed. The fluorescent products from the other catecholamines were also characterized as the corresponding 2-phenyl(4,5-dihydropyrrolo) [2,3-f ]benzoxazole derivatives on the basis of their mass spectral data.