FLUORESCENT PRODUCTS OF THE REACTION FOR THE DETERMINATION OF CATECHOLAMINES WITH 1,2-DIPHENYLETHYLENEDIAMINE

被引:21
作者
NOHTA, H [1 ]
LEE, MK [1 ]
OHKURA, Y [1 ]
机构
[1] KYUSHU UNIV,FAC PHARMACEUT SCI,62 MAIDASHI,HIGASHI KU,FUKUOKA 812,JAPAN
关键词
FLUOROMETRY; MASS SPECTROMETRY; CATECHOLAMINES; DOPAMINE; EPINEPHRINE; NOREPINEPHRINE;
D O I
10.1016/0003-2670(92)85015-X
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The fluorescent product formed in the reaction between epinephrine and 1,2-diphenylethylenediamine was determined to be 2-phenyl(4,5-dihydro-4-hydroxy-1-methylpyrrolo) [2,3-f]benzoxazole. The difference in the mechanisms of the reactions of 1,2-diphenylethylenediamine and ethylenediamine with epinephrine is discussed. The fluorescent products from the other catecholamines were also characterized as the corresponding 2-phenyl(4,5-dihydropyrrolo) [2,3-f ]benzoxazole derivatives on the basis of their mass spectral data.
引用
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页码:137 / 139
页数:3
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