ALKYL RADICALS FROM T-BUTYL ESTERS THROUGH PHOTOINDUCED ELECTRON-TRANSFER

被引：11

作者：

FASANI, E

PEVERALI, D

ALBINI, A

机构：

[1] Dipartimento di Chimica Organica, 27100 Pavia

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 49期

关键词：

D O I：

10.1016/0040-4039(94)88486-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl radicals are obtained under mild conditions from 1,2,1,5-benzenetetracarbonitrile SET photosensitized fragmentation of t-butyl esters. The same process occurs with undissociated carboxylic acids.

引用

页码：9275 / 9278

页数：4

共 15 条

[1] A NEW METHOD IN RADICAL CHEMISTRY - GENERATION OF RADICALS BY PHOTOINDUCED ELECTRON-TRANSFER AND FRAGMENTATION OF THE RADICAL-CATION [J].

ALBINI, A ;

MELLA, M ;

FRECCERO, M .

TETRAHEDRON, 1994, 50 (03) :575-607

[2]

ALBINI A, 1993, TOP CURR CHEM, V168, P143

[3] PHOTODECARBOXYLATION OF CARBOXYLIC-ACIDS SENSITIZED BY TRIPLET BENZOPHENONE AND DUROQUINONE - FLASH-PHOTOLYSIS ELECTRON-SPIN RESONANCE AND CHEMICALLY-INDUCED DYNAMIC NUCLEAR-POLARIZATION NUCLEAR MAGNETIC-RESONANCE INVESTIGATION [J].

BOWERS, PR ;

MCLAUCHLAN, KA ;

SEALY, RC .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1976, (08) :915-921

[4] PHOTODECARBOXYLATION - MECHANISM AND SYNTHETIC UTILITY [J].

BUDAC, D ;

WAN, P .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1992, 67 (02) :135-166

[5] THE ROLE OF ELECTRON-TRANSFER PROCESSES IN THE PHOTOINDUCED DECARBOXYLATION REACTION OF ALPHA-OXO-CARBOXYLIC ACIDS [J].

DAVIDSON, RS ;

GOODWIN, D .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1982, (12) :1559-1564

[6]

DAVIDSON RS, 1972, J CHEM SOC P2, P1557

[7] PHOTOCHEMICAL-REACTIONS OF 9,10-ANTHRACENEDICARBONITRILE AND 1,4-NAPHTHALENEDICARBONITRILE IN ACETONITRILE IN THE PRESENCE OF BASES [J].

FRECCERO, M ;

MELLA, M ;

ALBINI, A .

TETRAHEDRON, 1994, 50 (07) :2115-2130

[8] REDUCTION OF 10-METHYLACRIDINIUM ION WITH FATTY-ACIDS BY PHOTOINDUCED ELECTRON-TRANSFER REACTIONS [J].

FUKUZUMI, S ;

KITANO, T ;

TANAKA, T .

CHEMISTRY LETTERS, 1989, (07) :1231-1234

[9] EXTINCTION COEFFICIENT AND RECOMBINATION RATE OF BENZYL RADICALS .1. PHOTOLYSIS OF SODIUM PHENYLACETATE [J].

MEIGGS, TO ;

GROSSWEI.LI ;

MILLER, SI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (23) :7981-&

[10] PHOTOCHEMICAL-REACTION OF BENZENE-1,2,4,5-TETRACARBONITRILE WITH THE KETALS OF CYCLIC AND BICYCLIC KETONES [J].

MELLA, M ;

FRECCERO, M ;

ALBINI, A .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (05) :1047-1052

← 1 2 →