POLYCONDENSED NITROGEN-HETEROCYCLES .25. AMINOPYRROLO[1,2-F]-PHENANTHRIDINES BY DECOMPOSITION OF 2-(3-AZIDOPHENYL)-1-ARYLPYRROLES .1.

被引：8

作者：

ALMERICO, AM ^{[1
]}

CIRRINCIONE, G ^{[1
]}

DATTOLO, G ^{[1
]}

AIELLO, E ^{[1
]}

Mingoia, F ^{[1
]}

机构：

[1] CNR, IST CHIM & TECNOL PROD NAT, I-90123 PALERMO, ITALY

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1994年 / 31卷 / 01期

关键词：

D O I：

10.1002/jhet.5570310132

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acid catalyzed decomposition of the azido derivatives 4a-c gave rise to amino-hydroxy-phenylpyrroles of type 7 and 8 upon hydrolysis of the intermediate aryl nitrenium ions, together with the hydrogen abstraction compounds of type 3. The aminopyrrolo[1,2-f]phenanthridines 10, 11, and 12 were obtained by treatment with TFMSA of the azide 4d in which the ring being attacked was made more nucleophilic by the introduction of the methoxy group.

引用

页码：193 / 198

页数：6

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