POTASSIUM EXCHANGED LAYERED ZIRCONIUM-PHOSPHATE AS BASE CATALYST IN THE SYNTHESIS OF 2-NITROALKANOLS

被引：31

作者：

COSTANTINO, U ^{[1
]}

CURINI, M ^{[1
]}

MARMOTTINI, F ^{[1
]}

ROSATI, O ^{[1
]}

PISANI, E ^{[1
]}

机构：

[1] UNIV PERUGIA, FAC FARM, IST CHIM ORGAN, I-06123 PERUGIA, ITALY

来源：

CHEMISTRY LETTERS | 1994年 / 12期

关键词：

D O I：

10.1246/cl.1994.2215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of 2-nitroalkanols from nitroalkanes and aldehydes occurs efficiently, in mild conditions without solvent, when mediated by layered Zr(KOPO3)(2). The reaction has been tested in the preparation of ten different nitroalkanols and the data obtained seem to indicate that not only the surface but also the interlayer =P-O-K+ groups are involved in the catalytic process.

引用

页码：2215 / 2218

页数：4

共 20 条

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