ONE-STEP FORMATION OF ETHYL METHYL KETONE FROM 1-BUTENE AND WATER ON ULTRASTABLE Y-TYPE ZEOLITE CATALYST

被引：5

作者：

MORI, H

MIZUNO, N

TAJIMA, M

KAGAWA, S

IWAMOTO, M

机构：

[1] HOKKAIDO UNIV,CTR CATALYSIS RES,SAPPORO,HOKKAIDO 060,JAPAN

[2] MIYAKONOJO NATL COLL TECHNOL,DEPT IND CHEM,MIYAKONOJO 885,JAPAN

[3] NAGASAKI UNIV,FAC ENGN,DEPT IND CHEM,NAGASAKI 852,JAPAN

来源：

CATALYSIS LETTERS | 1991年 / 10卷 / 1-2期

关键词：

ETHYL METHYL KETONE; ULTRASTABLE Y-TYPE ZEOLITE; PENTACOORDINATED ALUMINUM; ACID-BASE CATALYSIS;

D O I：

10.1007/BF00764734

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Proton exchanged ultrastable Y-type zeolite with silica/alumina = 40 showed a pronounced catalytic activity for the formation of ethyl methyl ketone directly from 1-butene and water. The formation rate of ethyl methyl ketone was much higher than those on MoO3-based catalysts in the oxidation of 1-butene by oxygen. It was suggested that the basic site necessary for the formation of ethyl ketone directly from 1-butene and water would be the pentacoordinated Al.

引用

页码：35 / 40

页数：6

共 10 条

[1] THE FRAMEWORK CHEMISTRY OF ZEOLITES - AL-27 MASNMR OF EXTRALATTICE TETRAHEDRAL ALUMINUM SPECIES [J].