PREPARATION OF PZT POWDERS FROM METAL ALKOXIDES

被引：93

作者：

HIRASHIMA, H

ONISHI, E

NAKAGAWA, M

机构：

[1] Department of Applied Chemistry, Faculty of Science and Technology, Keio University, Kohoku-ku, Yokohama, 223, 3-14-1, Hiyoshi

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1990年 / 121卷 / 1-3期

关键词：

D O I：

10.1016/0022-3093(90)90166-J

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Fine powders of PZT, [Zr]/[Ti] = 53/47 and 55/45 in mol ratio, were prepared from Pb(isoC3H7O)2, Zr(nC4H9O)4 and Ti(isoC3H7O)4 through simultaneous hydrolysis in alcohol solutions. Spherical and X-ray-amorphous powders were obtained by hydrolysis in ethanol solution at temperatures below 76°C. After calcination at 400°C for 72 h, diffraction peaks of PZT were observed. During the calcination, an intermediate phase, cubic Pb2Ti2O6, was found. When the hydrolysis was carried out in n-propanol at 95°C, irregular shaped particles were obtained. After drying at 90°C, diffraction peaks of PZT and of the intermediate phase were observed. © 1990.

引用

页码：404 / 406

页数：3

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