SYNTHESIS OF BETA-ENAMINOPERFLUOROESTERS, BETA-IMINO-ALPHA-HYDROPERFLUOROESTERS AND BETA-AMIDO-ALPHA-FLUOROESTERS

被引：15

作者：

PORTELLA, C

IZNADEN, M

机构：

[1] Réarrangements Thermiques et Photochimiques, Unité Associée au CNRS, Faculté des Sciences, 51062 Reims Cédex

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 51卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)80302-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compounds were synthesized in a high yield one pot procedure from alpha-H-perfluoroesters and aliphatic amines. From primary amines, the beta-imino tautomer was shown to be more stable than the enamino one, which is only observed with butanoic derivatives, as a minor component. The reaction did not occur with aromatic amines. In the propanoic series, the reaction product was the beta-amido-alpha-fluoroester.

引用

页码：1 / 20

页数：20

共 17 条

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