STEREOSELECTIVE MOLECULAR RECOGNITION OF ENANTIOMERIC COBALT(III) COMPLEXES BY NOVEL PHOTOSENSITIZERS OF HELICAL RUTHENIUM(II) COMPLEXES

被引：7

作者：

OHKUBO, K

HAMADA, T

ISHIDA, H

FUKUSHIMA, M

WATANABE, M

机构：

[1] Kumamoto Univ, Kumamoto, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 89卷 / 1-2期

关键词：

CHIRAL PHOTOSENSITIZERS; HELICITY; PYRIDINE DERIVATIVES; RUTHENIUM; STEREOSELECTIVE QUENCHING;

D O I：

10.1016/0304-5102(93)E0341-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The stereoselective quenching of helical Ru(II) complexes with DELTA or LAMBDA-Co(III) complexes was controlled by the molecular helicities of the both reactants. The quenching rate constant and stereoselectivity were affected by the EtOH content in the EtOH/H2O solvent with the maximum quenching rate ratio of k(q)DELTA/k(q)LAMBDA = 1.28.

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页码：L5 / L10

页数：6

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