CHEMICAL MODIFICATION OF HECTORITE BY INTERLAYER POLYMERIZATION OF (3-AMINOPROPYL)TRIMETHOXYSILANE

被引：7

作者：

IWAI, M ^{[1
]}

SHOJI, H ^{[1
]}

SHIMAZU, S ^{[1
]}

UEMATSU, T ^{[1
]}

机构：

[1] CHIBA UNIV, FAC ENGN, DEPT APPL CHEM, 1-33 YAYOI CHO, INAGE KU, CHIBA 263, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.403

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Interlayer-polymerization of (3-aminopropyl)trimethoxysilane (APMS) was carried out in the interlayer of lithium hectorite(LHT), and hectorites modified by ''tuning pest'' such as alkylammonium hectorite(CnNHT) and pyridinium hectorite (PyHT). XRD measurements revealed that the polymer-LHT complex showed no d001 diffraction peaks, while the polymer-CnNHT and -PyHT complexes had definite basal spacings depending on the guest or the amount of APMS. The polymer-clay complexes were characterized by means of Si-29 CP/MAS NMR and Fr-IR spectra.

引用

页码：403 / 406

页数：4