IPY(2)BF(4) IS ALSO A USEFUL REAGENT FOR STEREOSPECIFIC IODINE-SILICON EXCHANGE IN OPEN-CHAIN TRIMETHYLSILYLALKENES

被引:23
作者
BARLUENGA, J
ALVAREZGARCIA, LJ
GONZALEZ, JM
机构
[1] Instituto Universitario de Química Organometálica Enrique Moles, Universidad de Oviedo, 33071 Oviedo
关键词
D O I
10.1016/0040-4039(95)00199-M
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of the title monosubstituted vinylsilanes with IPy(2)BF(4)/HBF4 gives iodoalkenes through the ipso-substitution process with stereospecific retention of configuration.
引用
收藏
页码:2153 / 2156
页数:4
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