A COPPER-COPPER BOND BY INTENT

被引：58

作者：

HARDING, C

NELSON, J

SYMONS, MCR

WYATT, J

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

[2] OPEN UNIV,DEPT CHEM,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND

[3] UNIV ESSEX,DEPT CHEM & BIOL CHEM,COLCHESTER CO4 3SQ,ESSEX,ENGLAND

[4] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 21期

关键词：

D O I：

10.1039/c39940002499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ESR spectra for a series of binuclear trigonal bipyramidal copper complexes show that the SOMO is largely composed of the two equivalent d(z)2 orbitals on copper; the temperature independence of the ESR parameters shows that this is a relatively strong bond, and since the unpaired electron is antibonding, the sigma-bond must be even stronger; these results are contrasted with the more common situation that arises when the electron is shared between two d(x)2(-y)2 type orbitals.

引用

页码：2499 / 2500

页数：2

共 8 条

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[2] BINUCLEAR COMPLEXES OF MACROCYCLIC LIGANDS - MIXED-VALENCE COPPER(II)-COPPER(I) COMPLEX WHICH EXHIBITS UNUSUAL TEMPERATURE-DEPENDENT BEHAVIOR [J].