ELECTROCHEMICAL AND SPECTRAL RECOGNITION OF CHLORIDE-IONS BY NOVEL ACYCLIC RUTHENIUM(II) BIPYRIDYL RECEPTOR COMPLEXES

被引：18

作者：

BEER, PD

MORTIMER, RJ

STRADIOTTO, NR

SZEMES, F

WEIGHTMAN, JS

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

[2] LOUGHBOROUGH UNIV TECHNOL,LOUGHBOROUGH,LEICS,ENGLAND

来源：

ANALYTICAL PROCEEDINGS | 1995年 / 32卷 / 10期

关键词：

D O I：

10.1039/ai9953200419

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The electrochemical and spectral recognition of chloride anions by novel acyclic ruthenium(II) bipyridyl receptor complexes is demonstrated. The low energy metal-to-ligand charge-transfer (MLCT) emission band of the complexes and inherent sensitivity of the technique suggests that fluorescence emission spectroscopy offers particular promise in analytical applications. The principle of anion recognition based on the suitable design of the receptor complexes will be applicable to a range of analytes.

引用

页码：419 / 421

页数：3

共 16 条

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