SYNTHESIS AND ELECTROCHEMICAL CHARACTERIZATION OF NEW POLYMER ELECTROLYTES BASED ON DIOXOLANE HOMO-POLYMERS AND COPOLYMERS

被引：23

作者：

GOULART, G

SANCHEZ, JY

ARMAND, M

机构：

[1] Laboratoire d'Ionique et d'Electrochimie du Solide de Grenoble E.N.S.E.E.G., 38402 Saint Martin d'Heres Cedex

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 09期

关键词：

POLYMER ELECTROLYTE; CONDUCTIVITY; POLYDIOXOLANE; COPOLYMERS;

D O I：

10.1016/0013-4686(92)80117-5

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Several polyacetals have been investigated as host polymer, for polymer electrolytes. The cationic polymerization and copolymerization of dioxolane (DXL) and 4-methyl, dioxolane (MDXL) are reported. If PDXL is a semi-crystalline polymer, an amorphous polymer electrolyte at room temperature is obtained for some LiTFSI concentrations. The PMDXL as well as the copolymer Poly(DXL-MDXL) appear completely amorphous. Nevertheless, due to salt desolvation or polymer degradation, the PMDXL/LiTFSI conductivities drop when the temperature increases.

引用

页码：1589 / 1592

页数：4

共 11 条

[1] LI+-CONDUCTIVE POLYMER ELECTROLYTES DERIVED FROM POLY(1,3-DIOXOLANE) AND POLYTETRAHYDROFURAN [J].

ALAMGIR, M ;

MOULTON, RD ;

ABRAHAM, KM .

ELECTROCHIMICA ACTA, 1991, 36 (5-6) :773-782

[2] SOLUBILITY PARAMETER AND RANDOM-COIL DIMENSIONS OF POLY(1,3-DIOXOLANE) [J].

ALAMO, R ;

FATOU, JG ;

BELLO, A .

POLYMER JOURNAL, 1983, 15 (07) :491-498

[3]

ARMAND M, 1990, 2ND P INT S POL EL L, P39

[4]

CHWIALKOWSKA W, 1982, MAKROMOL CHEM, V183, P753

[5] THERMAL-DEGRADATION OF POLY(4-METHYL-1,3-DIOXOLANE) [J].

DIAB, MA ;

CHIEN, JCW .

ACTA POLYMERICA, 1989, 40 (09) :586-590

[6]

FIRAT Y, 1975, MAKROMOL CHEM, V176, P1179

[7]

GOULDARD G, 1990, 2ND P INT S POLYM EL, P99

[8]

OKADA M, 1975, MAKROMOL CHEM, V176, P859

[9]

OLEINIK EF, 1967, VYSOKOMOL SOEDIN A, V9, P2609

[10] STRUCTURAL STUDIES OF POLYFORMALS .2. CRYSTAL-STRUCTURE OF POLY-1,3-DIOXOLANE - MODIFICATION II [J].

SASAKI, S ;

TAKAHASHI, Y ;

TADOKORO, H .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1972, 10 (12) :2363-2378

← 1 2 →