HOMOGENEOUS HYDROFORMYLATION OF OLEFINS BY CIS-[PTCL2(PPH3)2]/SNCL2

被引:17
作者
MULLER, G
SAINZ, D
SALES, J
机构
来源
JOURNAL OF MOLECULAR CATALYSIS | 1990年 / 63卷 / 02期
关键词
D O I
10.1016/0304-5102(90)85141-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The catalytic activity of cis-[PtCl2(PPh3)2]/SnCl2 in the hydroformylation of different olefins (1-pentene, cyclopentene, cyclohexene, allyl benzene, styrene, methylacrylate, vinylacetate, allyl alcohol and acrylonitrile) has been studied. The results obtained with cyclopentene (79% hydroformylation; TOF 180 h-1) and allyl benzene (87% hydroformylation, TOF 220 h-1) are among the best reported thus far.
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页码:173 / 180
页数:8
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