REGIOSPECIFIC AND DIASTEREOSELECTIVE CROTYLATION OF ALDIMINES WITH CROTYLTRIFLUOROSILANES ACTIVATED BY FLUORIDE IONS

被引:31
作者
KIRA, M
HINO, T
SAKURAI, H
机构
关键词
D O I
10.1246/cl.1991.277
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aliphatic and aromatic aldimines are crotylated in a regiospecific and diastereoselective manner by the reacton with (E)- and (Z)-crotyltrifluorosilanes in the presence of cesium fluoride to give homoallylamines in high yields.
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页码:277 / 280
页数:4
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