UNUSUAL 1,3-REARRANGEMENT OF TRIMETHYLSILYL GROUP IN THE REACTION OF 2,4,6-TRIS[BIS(TRIMETHYLSILYL)METHYL]PHENYLLITHIUM

被引：19

作者：

TOKITOH, N ^{[1
]}

MATSUMOTO, T ^{[1
]}

SUZUKI, H ^{[1
]}

OKAZAKI, R ^{[1
]}

机构：

[1] UNIV TOKYO,FAC SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(00)78905-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,4,6-Tris[bis(trimethylsilyl)methyl]phenyllithium (TbLi) gave a novel 1,3-silicon rearrangement product above -30-degrees-C, while the treatment of TbLi with some electrophiles also afforded 1,3-silicon rearrangement products even at -78-degrees-C probably via single electron transfer mechanism.

引用

页码：2049 / 2052

页数：4

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