MANGANESE CARBONYL-COMPLEXES OF 2,5-DIMETHYLBISMOLYL - THE CRYSTAL AND MOLECULAR-STRUCTURE OF (ETA(1)-2,5-DIMETHYLBISMOLYL) MANGANESE PENTACARBONYL

被引：11

作者：

ASHE, AJ

KAMPF, JW

PURANIK, DB

机构：

[1] Department of Chemistry, The University of Michigan, Ann Arbor

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 447卷 / 02期

关键词：

D O I：

10.1016/0022-328X(93)80238-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(Eta-1-2,5-Dimethylbismolyl)manganese pentacarbonyl (8) has been obtained from the reaction of 1-phenyl-2,5-dimethylbismole with lithium followed by BrMn(CO)5. Heating 8 to its melting point causes the loss of CO to produce (eta5-2,5-dimethylbismolyl)manganese tricarbonyl. Compound 8 crystallizes in the monoclinic crystal system, space group P2(1) (No. 4) with a = 6.838(2) angstrom, b = 6.424(1) angstrom, c = 15.787(4) angstrom, beta = 95.68(2)-degrees, V = 690.1(2) angstrom3 and Z = 2. A full structure has been determined and is compared with those of analogous compounds.

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页码：197 / 201

页数：5

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