ENZYMATIC RESOLUTION OF OPTICALLY-ACTIVE ALIPHATIC CYANOHYDRINS

被引：25

作者：

KANERVA, LT

KILJUNEN, E

HUUHTANEN, TT

机构：

[1] Department of Chemistry, University of Turku

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(00)80102-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantioselective acylation of cyanohydrins 1a-9a by PPL catalysis and deacylation of propionates 1b-9b by CCL catalysis in toluene proceed from good (E 15-20) to excellent (E > 30) enantioselectivity. A solvent has a clear effect on enzymatic enantioselectivity.

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页码：2355 / 2361

页数：7

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