DUAL-POROSITY SILICA-GELS BY POLYMER-INCORPORATED SOL-GEL PROCESS

被引:35
作者
NAKANISHI, K
TAKAHASHI, R
SOGA, N
机构
[1] Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Kyoto
关键词
D O I
10.1016/S0022-3093(05)80632-5
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Pore characteristics of silica gels prepared by the polymer-incorporated alkoxide-based sol-gel process have been investigated. Micrometer-range Pore sizes could be controlled by changing several reaction parameters, such as molecular weight or concentration of polymer or reaction temperature, that affect the domain formation process due to an occurrence of phase separation during a gel-forming reaction. The volume fraction and size distribution of nanometer-range pores after a heat treatment were varied by different solvent exchange treatments of a wet gel.
引用
收藏
页码:291 / 295
页数:5
相关论文
共 10 条
[1]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[2]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[3]  
GREGG SJ, 1982, ADSORPTION SURFACE A, pCH4
[4]   An adsorption method for the determination of the area of a solid without the assumption of a molecular area, and the area occupied by nitrogen molecules on the surfaces of solids [J].
Harkins, WD ;
Jura, G .
JOURNAL OF CHEMICAL PHYSICS, 1943, 11 (09) :431-432
[5]   ATTEMPTS TO AVOID CRACKS DURING DRYING [J].
MIZUNO, T ;
NAGATA, H ;
MANABE, S .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 100 (1-3) :236-240
[6]   PHASE-SEPARATION IN SILICA SOL-GEL SYSTEM CONTAINING POLYACRYLIC-ACID .1. GEL FORMATION BEHAVIOR AND EFFECT OF SOLVENT COMPOSITION [J].
NAKANISHI, K ;
SOGA, N .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 139 (01) :1-13
[7]   PORE SURFACE CHARACTERISTICS OF MACROPOROUS SILICA-GELS PREPARED FROM POLYMER-CONTAINING SOLUTION [J].
NAKANISHI, K ;
SAGAWA, Y ;
SOGA, N .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1991, 134 (1-2) :39-46
[8]   PHASE-SEPARATION IN SILICA SOL-GEL SYSTEM CONTAINING POLYACRYLIC-ACID .2. EFFECTS OF MOLECULAR-WEIGHT AND TEMPERATURE [J].
NAKANISHI, K ;
SOGA, N .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 139 (01) :14-24
[9]   PHASE-SEPARATION IN GELLING SILICA ORGANIC POLYMER-SOLUTION - SYSTEMS CONTAINING POLY(SODIUM STYRENESULFONATE) [J].
NAKANISHI, K ;
SOGA, N .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (10) :2518-2530
[10]  
Nakanishi K., UNPUB