NOVEL CERAMIC AND ORGANOMETALLIC DEPOLYMERIZATION PRODUCTS FROM POLY(FERROCENYLSILANES) VIA PYROLYSIS

被引：102

作者：

TANG, BZ

PETERSEN, R

FOUCHER, DA

LOUGH, A

COOMBS, N

SODHI, R

MANNERS, I

机构：

[1] UNIV TORONTO,DEPT CHEM,80 ST GEORGE ST,TORONTO M5S 1A1,ONTARIO,CANADA

[2] UNIV TORONTO,CTR BIOMAT,TORONTO M5S 1A1,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 06期

关键词：

D O I：

10.1039/c39930000523

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When heated at 500-degrees-C under nitrogen the poly(ferrocenylsilanes) [Fe(eta-C5H4)2(SiR2)]n (1; R = Me, or 2; R = Ph) yield magnetic iron silicon carbide ceramics together with a orange-yellow sublimate which, in the case of 1, was shown to contain the unusual unsymmetrical dimer [Fe(eta-C5H4)2(mu-SiMe2)2(eta-C5H3)Fe(eta-C5H5)] 3 by single crystal X-ray diffraction.

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页码：523 / 525

页数：3

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