REDOX CATALYSIS IN FREE-RADICAL REACTIONS - NEW, SIMPLE, CONVENIENT INTRAMOLECULAR HOMOLYTIC AROMATIC SUBSTITUTIONS

被引：17

作者：

ARANEO, S ^{[1
]}

FONTANA, F ^{[1
]}

MINISCI, F ^{[1
]}

RECUPERO, F ^{[1
]}

SERRI, A ^{[1
]}

机构：

[1] POLITECN MILAN,DIPARTIMENTO CHIM,I-20131 MILAN,ITALY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期

关键词：

D O I：

10.1016/0040-4039(95)00746-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three new general, simple and convenient procedures of intramolecular homolytic aromatic substitution leading to homocyclic and heterocyclic compounds have been developed by addition of aryl or nucleophilic alkyl radicals to alkenes conjugated with electron-withdrawing groups in the presence of metal salt redox systems.

引用

页码：4307 / 4310

页数：4

共 10 条

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[8] KHARASCH AND METALLOPORPHYRIN CATALYSIS IN THE FUNCTIONALIZATION OF ALKANES, ALKENES, AND ALKYLBENZENES BY T-BUOOH - FREE-RADICAL MECHANISMS, SOLVENT EFFECT, AND RELATIONSHIP WITH THE GIF REACTION
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[9] MINISCI F, 1984, FUNDAMENTAL RES HOMO, P173
[10] Minisci F., 1987, ORGANIC SYNTHESIS MO, P229

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