C-2-SYMMETRIC 1,2-DIAMINE/COPPER(II) TRIFLUOROMETHANESULFONATE COMPLEXES AS CHIRAL CATALYSTS - ASYMMETRIC CYCLOPROPANATIONS OF STYRENE WITH DIAZO ESTERS

被引：53

作者：

KANEMASA, S ^{[1
]}

HAMURA, S ^{[1
]}

HARADA, E ^{[1
]}

YAMAMOTO, H ^{[1
]}

机构：

[1] KYUSHU UNIV,INTERDISCIPLINARY GRAD SCH ENGN SCI,DEPT MOLEC SCI & TECHNOL,KASUGA,FUKUOKA 816,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)78403-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Styrene and diazo esters react in the presence of copper(II) trifluoromethanesulfonate (1 mol%) and (1S,2S)-N,N'-di(mesitylmethyl)-1,2-diphenyl-1,2-ethanediamine (2 - 3 mol%) to give 2-phenyl-1-cyclopropanecarboxylates in good to excellent optical yields. This reaction has been applied to the synthesis of chrythanthemic acid.

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页码：7985 / 7988

页数：4

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