STABILIZATION OF REACTANTS IN A WEAKLY-BOUND COMPLEX - OH-H-2 AND OH-D-2

被引：40

作者：

LOOMIS, RA

LESTER, MI

机构：

[1] Department of Chemistry, University of Pennsylvania, Philadelphia

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 10期

关键词：

D O I：

10.1063/1.470678

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Binary complexes of OH X(2) Pi and H-2/D-2 have been stabilized in a shallow well below the activation barrier to the hydrogen abstraction reaction and identified by laser-induced fluorescence in the OH A (2) Sigma(+)-X (2) Pi 1-0 spectral region. The characteristics of the OH (X (2) Pi, A (2) Sigma(+)) + H-2/D-2 potentials are in accord with ab initio predictions. (C) 1995 American Institute of Physics.

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页码：4371 / 4374

页数：4

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