SYNTHESIS AND SOLUTION PROPERTIES OF COMB-LIKE POLY(MONO-NORMAL-ALKYL-ITACONATES) .2. POLY(MONODODECYL ITACONATE)

被引：38

作者：

LEON, A

GARGALLO, L

RADIC, D

HORTA, A

机构：

[1] CATHOLIC UNIV CHILE,FAC QUIM 502,CASILLA 6177,SANTIAGO,CHILE

[2] UNIV SANTIAGO DE COMPOSTELA,FAC CIENCIA,DEPT QUIM,SANTIAGO,SPAIN

[3] UNIV DISTANCIA,DEPT QUIM FIS,E-28040 MADRID,SPAIN

来源：

POLYMER | 1991年 / 32卷 / 04期

关键词：

COMB-LIKE POLYMER; POLY(MONOALKYL ITACONATE); STATISTICAL SEGMENT LENGTH; SOLUTION PROPERTIES;

D O I：

10.1016/0032-3861(91)90492-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The monoester of itaconic acid with n-dodecyl alcohol was synthesized and polymerized. Polymer fractions were characterized by viscometry, size exclusion chromatography (s.e.c.) and light scattering. Thermodynamic and dimensional parameters were determined and calculated. The results found are 67 angstrom for the statistical segment length l and 8 angstrom for the chain diameter d. These results are compared with those reported previously for a similar compound.

引用

页码：761 / 763

页数：3

共 14 条

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[2]

BALCER BR, 1952, J ORG CHEM, V17, P122

[3] NEW METHOD FOR ESTIMATING THE PARAMETERS OF THE WORMLIKE CHAIN MODEL FROM THE INTRINSIC-VISCOSITY OF STIFF-CHAIN POLYMERS [J].