MASS-ANALYZED THRESHOLD IONIZATION SPECTROSCOPY OF AL-AR

被引：50

作者：

WILLEY, KF ^{[1
]}

YEH, CS ^{[1
]}

DUNCAN, MA ^{[1
]}

机构：

[1] UNIV GEORGIA,DEPT CHEM,ATHENS,GA 30602

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 211卷 / 01期

关键词：

D O I：

10.1016/0009-2614(93)80065-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mass-analyzed threshold ionization (MATI) spectroscopy is applied for the first time to a metal van der Waals complex, Al-Ar. The experimental configuration for MATI uses a time-of-flight mass spectrometer, oriented perpendicular to the molecular beam axis, without modification of any components. The vibrationally resolved spectrum yields a frequency of omega(e)'' = 67 cm-1 for the ground state of Al+-Ar, and a value of DELTAG1/2'' = 39 cm-1 for neutral Al-Ar.

引用

页码：156 / 160

页数：5

共 22 条

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