POLYCONDENSATION OF AMINOSILANES IN METHANOL

被引：33

作者：

ROUSSEAU, F

POINSIGNON, C

GARCIA, J

POPALL, M

机构：

[1] INST NATL POLYTECH GRENOBLE,ECOLE NATL SUPER ELECTROCHIM & ELECTROME GRENOBLE,F-38402 ST MARTIN DHERES,FRANCE

[2] FRAUNHOFER INST SILICATFORSCH,W-8700 WURZBURG,GERMANY

[3] UNIV GRENOBLE 1,ETUD DYNAM & STRUCT SELECT LAB,F-38041 GRENOBLE,FRANCE

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 05期

关键词：

D O I：

10.1021/cm00053a004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polycondensation of (3-aminopropyl)trimethoxysilane and ((trimethoxysilyl)propyl)diethylenetriamine in methanol was studied using Si-29 NMR spectroscopy, small-angle X-ray scattering, and viscosity measurements. Calculations based on Si-29 NMR data show a cluster-cluster growth mechanism is present. Differences in reactivity and in the structures obtained will be discussed.

引用

页码：828 / 839

页数：12

共 50 条

[1]

Schmidt H., Better Ceramics through Chemistry, 171, (1990)

[2]

Popall M., Schmidt H., Processing T.E.C. Grenoble, (1988)

[3]

Schmidt H., Seiferling B., Better Ceramics through Chemistry 11 Mat. Res. Soc. Symp. Proc., 73, (1986)

[4]

Ravaine D., Armand M., Charbouillot Y., Hammou A., (1986)

[5]

Charbouillot Y., Ravaine D., Armand M., Poinsignon C., J. Non-Cryst. Solids, 103, (1988)

[6]

Charbouillot Y., (1987)

[7]

Nishiyama N., Horie K., Asakura T., J. Appl. Polym. Sci., 34, (1987)

[8]

Ishida H., Suzuki Y., Compos. Interfaces, Proc. Int. Conf. 1st, (1986)

[9]

Kang H.-J., Meesiri W., Blum D., F. D. Mater. Sci. Eng., A126, (1990)

[10]

Hoebbel D., Pitsch I., Jancke H., Costisella B.Z., Anorg. Allg. Chem., 588, (1990)

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