SOLUBILITY PROPERTIES IN POLYMERS AND BIOLOGICAL MEDIA .10. THE SOLUBILITY OF GASEOUS SOLUTES IN POLYMERS, IN TERMS OF SOLUTE POLYMER INTERACTIONS

被引:35
作者
ABRAHAM, MH
GRELLIER, PL
MCGILL, RA
DOHERTY, RM
KAMLET, MJ
HALL, TN
TAFT, RW
CARR, PW
KOROS, WJ
机构
[1] USN,CTR SURFACE WEAP,WHITE OAK LAB,SILVER SPRING,MD 20910
[2] UNIV CALIF IRVINE,DEPT CHEM,IRVINE,CA 92717
[3] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455
[4] UNIV TEXAS,DEPT CHEM ENGN,AUSTIN,TX 78712
关键词
GASES - Solubility - MATHEMATICAL MODELS - POLYMETHYL METHACRYLATE - POLYVINYL ACETATE;
D O I
10.1016/0032-3861(87)90453-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The sorption and diffusion of gases and vapors into and through polymers is of considerable practical and theoretical importance. Construction of general equations that describe the sorption of gaseous solutes into polymers would represent a significant advance, especially if it were possible to ascertain whether or not equations that describe the behavior of solutes in nonpolymeric systems are equally applicable to polymers. In this paper a general equation has been used to describe solubility properties of a wide range of gaseous solutes in polymers.
引用
收藏
页码:1363 / 1369
页数:7
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