THE NONLINEAR RESONANCE QUISTOR .1. POTENTIAL DISTRIBUTION IN HYPERBOLOIDAL QUISTORS

被引:38
作者
WANG, Y
FRANZEN, J
机构
[1] Bruker-Franzen Analytik GmbH, 2800 Bremen 33
来源
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1992年 / 112卷 / 2-3期
关键词
QUISTOR; MULTIPOLE FIELDS; HYPERBOLIC ANGLE;
D O I
10.1016/0168-1176(92)80002-I
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Non-linear resonance QUISTORS are generated by the superposition of multipole fields on the basic quadrupolar field. An easy way to superimpose even multiples is the variation of the hyperbolic angle of the classical Paul QUISTOR. In this first paper of a series, an analytical expression is deduced for the potential distribution in such boundaries, using the variational calculus method described by Ritz. The resulting complex potential formula can be reduced with sufficient accuracy to the simple form: u(r,z) = V0/r0(2)(r2 - 0z2) + c(2 - 0)V0[r0(4) - (r2 - theta-z2)2/r0(4)]exp(- theta-r2 + b-theta-z2)/r0(2) containing only three constants a, b, and c, which depend almost linearly on the parameter theta = r0(2)/z0(2) for the hyperbolic angle. The dependency of the constants is presented in graphical form. The method for the derivation of the potential is very general and can be used with other complex boundaries, even including space charge distributions. This potential distribution, among others, will be used in future papers to study the basic mass analysis principles of non-linear resonance QUISTORS.
引用
收藏
页码:167 / 178
页数:12
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