EFFECT OF REACTION CONDITIONS ON THE RADICAL-ADDITION OF PERFLUOROHEXYL IODIDE TO VINYL-ACETATE

被引：15

作者：

NAPOLI, M

FRACCARO, C

CONTE, L

GAMBARETTO, GP

LEGNARO, E

机构：

[1] Institute of Industrial Chemistry, University of Padua, 35131 Padua

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1992年 / 57卷 / 1-3期

关键词：

D O I：

10.1016/S0022-1139(00)82834-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The radical addition of perfluorohexyl iodide to vinyl acetate to give an iodine-containing adduct has been studied under different conditions in order to define their influence on the reaction. Experiments have been carried out varying parameters (molar ratio of reagents, weight percent of initiator, reaction time, temperature, oxygen removal) and studying the effects on the perfluoroalkyl iodide conversion and on the adduct yield. From the experimental data obtained, the conditions required to optimize the adduct yield have been defined.

引用

页码：219 / 227

页数：9

共 7 条

[1] RADICAL ADDITION OF IODOPERFLUOROALKANES TO VINYL AND ALLYL MONOMERS [J].