DINUCLEAR 5-CO-ORDINATE ZINC-COMPLEXES BRIDGED BY A PHOSPHATE MONOESTER OR AN INORGANIC-PHOSPHATE GROUP

被引:34
作者
ADAMS, H [1 ]
BAILEY, NA [1 ]
FENTON, DE [1 ]
HE, QY [1 ]
机构
[1] UNIV SHEFFIELD,DEPT CHEM,DAINTON BLDG,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 04期
关键词
D O I
10.1039/dt9950000697
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two dinuclear five-co-ordinated zinc complexes, derived from tris[(2-pyridyl)methyl]amine and bridged by a phosphate monoester or an inorganic phosphate group respectively, have been synthesized; the structure of the former has been established by X-ray crystallography and shows the bridging mode of the phosphate to be syn-anti whereas in alkaline phosphatase it is syn-syn.
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页码:697 / 699
页数:3
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