PREPARATION OF NEW VANADIUM(II) IODIDES AND CRYSTAL-STRUCTURE OF HEXAKIS(ACETONITRILE)VANADIUM(II) (TETRAIODIDE)

被引:30
作者
HITCHCOCK, PB
HUGHES, DL
LEIGH, GJ
SANDERS, JR
DESOUZA, J
MCGARRY, CJ
LARKWORTHY, LF
机构
[1] UNIV SUSSEX,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND
[2] UNIV SURREY,DEPT CHEM,GUILDFORD GU2 5XH,SURREY,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 24期
关键词
D O I
10.1039/dt9940003683
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of [VCl3(MeCN)(3)] with SiMe(3)I in acetonitrile under reflux yielded a vanadium(II) cation [V(MeCN)(6)](2+) with a counter ion I-4(2-). The latter is not symmetrical, though linear, and the reasons are discussed. The new compound diiodotetrakis (tetrahydrofuran)vanadium (II) is shown tb be a versatile precursor for vanadium diiodides, such as [VI2(Et(2)PCH(2)CH(2)PEt(2))(2)], the structure of which has also been determined.
引用
收藏
页码:3683 / 3687
页数:5
相关论文
共 36 条
[1]   DINITROGEN COMPLEXES OF TUNGSTEN WITH BULKY PHOSPHINE CO-LIGANDS - PREPARATION AND CRYSTAL-STRUCTURES OF [(W(N2)2(PET2PH)3)2(MU-N2)], TRANS-[W(N2)2(PET2PH)4].C4H8O, AND "[W(ETA-6-C6H5PPRN2)(N-2)(PPRN2PH)2] AND THEIR REACTIONS TO GIVE HYDRAZINE OR AMMONIA [J].
ANDERSON, SN ;
RICHARDS, RL ;
HUGHES, DL .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (02) :245-252
[2]  
[Anonymous], 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]
[3]   CRYSTAL AND MOLECULAR-STRUCTURES OF 4 BIS(DIPHOSPHINE) COMPLEXES OF IRON(II) - BIS[1,2-BIS(DIETHYLPHOSPHINO)ETHANE]DI-IODOIRON(II), DICHLORO-BIS[O-PHENYLENEBIS(DIPHENYLPHOSPHINE)]IRON(II), BIS(ACETONITRILE)BIS-[ORTHO-PHENYLENEBIS(DIPHENYLPHOSPHINE)]IRON(II) DI-IODIDE, AND IODOBIS-[ORTHO-PHENYLENEBIS(DIPHENYLPHOSPHINE)]IRON(II) IODIDEE [J].
BARCLAY, JE ;
HILLS, A ;
HUGHES, DL ;
LEIGH, GJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (11) :2871-2877
[4]   BIS(INDENYL)VANADIUM(II) - ITS OXIDATION AND CARBONYLATION OF ITS CATION [J].
BOCARSLY, JR ;
FLORIANI, C ;
CHIESIVILLA, A ;
GUASTINI, C .
INORGANIC CHEMISTRY, 1987, 26 (12) :1871-1875
[5]   REACTIONS OF BIS(CYCLOPENTADIENYL)VANADIUM DERIVATIVES WITH NITROGEN MONO-OXIDE AND THE CRYSTAL-STRUCTURE OF AN OXO-BRIDGED NITROSYL COMPLEX OF VANADIUM [J].
BOTTOMLEY, F ;
DARKWA, J ;
WHITE, PS .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (07) :1435-1442
[6]   REACTIONS OF NITROGEN MONOXIDE AND DIOXYGEN WITH BIS(PENTAMETHYLCYCLOPENTADIENYL)VANADIUM DIHALIDES - PREPARATION AND STRUCTURES OF OXO DERIVATIVES OF (PENTAMETHYLCYCLOPENTADIENYL)VANADIUM [J].
BOTTOMLEY, F ;
DARKWA, J ;
SUTIN, L ;
WHITE, PS .
ORGANOMETALLICS, 1986, 5 (11) :2165-2171
[7]   THE PREPARATION AND CRYSTAL AND MOLECULAR-STRUCTURES OF TRICHLOROBIS(METHYLDIPHENYLPHOSPHINE)VANADIUM(III) AND ITS ACETONITRILE ADDUCT [J].
BULTITUDE, J ;
LARKWORTHY, LF ;
POVEY, DC ;
SMITH, GW ;
DILWORTH, JR .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10) :2253-2258
[8]   REACTION OF MOLECULAR-IODINE WITH CIS-DIHALO(2,2'-BIPYRIDYL)PLATINUM(II) AND CIS-DIHALO(1,10-PHENANTHROLINE)PLATINUM(II) - OXIDATIVE ADDITION AND INCLUSION COMPOUNDS [J].
BUSE, KD ;
KELLER, HJ ;
PRITZKOW, H .
INORGANIC CHEMISTRY, 1977, 16 (05) :1072-1076
[9]   BIS(ARENE)VANADIUM(0) COMPLEXES AS A SOURCE OF VANADIUM(II) DERIVATIVES BY BOTH DISPROPORTIONATION OF THE [V(ETA-6-ARENE)2]+ CATIONS AND OXIDATION OF [V(ETA-6-ARENE)2] [J].
CALDERAZZO, F ;
DEBENEDETTO, GE ;
PAMPALONI, G ;
MOSSMER, CM ;
STRAHLE, J ;
WURST, K .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) :73-81
[10]  
CASEY AT, 1972, INORG SYNTH, V13, P165