INCLUSION COMPLEX BETWEEN URANYL AND AN AZACROWN - STRUCTURE OF [UO2(18-AZACROWN-6)]2+.2CF3SO3-

被引：24

作者：

NIERLICH, M

SABATTIE, JM

KELLER, N

LANCE, M

VIGNER, JD

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193006717

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, (1,4,7,10,13,16-hexaazacycloocta-decane)dioxouranium bis(trifluoromethylsulfonate), [UO2(C12H30N6)]2+.2CF3SO3-, is composed of [UO2(18-azacrown-6)]2+ and CF3SO3- ions. In the cation, the uranyl is bonded to the six N atoms of the crown in a hexagonal bipyramidal coordination. This is the first reported uranyl hexaazacrown inclusion complex.

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页码：52 / 54

页数：3

相关论文

共 15 条

[1] DISCUSSION ON THE COMPLEXING ABILITY OF THE URANYL-ION WITH SEVERAL CROWN ETHERS AND CRYPTANDS IN WATER AND IN PROPYLENE CARBONATE [J].

BRIGHLI, M ;

FUX, P ;

LAGRANGE, J ;

LAGRANGE, P .

INORGANIC CHEMISTRY, 1985, 24 (01) :80-84

[2] URANYLPENTAPHYRIN - AN ACTINIDE COMPLEX OF AN EXPANDED PORPHYRIN [J].

BURRELL, AK ;

HEMMI, G ;

LYNCH, V ;

SESSLER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) :4690-4692

[3] INSERTION OF TRIVALENT URANIUM IN MACROCYCLIC CROWN-ETHERS - EXAFS AND X-RAY STRUCTURAL-ANALYSES [J].

DEJEAN, A ;

CHARPIN, P ;

FOLCHER, G ;

RIGNY, P ;

NAVAZA, A ;

TSOUCARIS, G .

POLYHEDRON, 1987, 6 (02) :189-195

[4] COMPLEXES BETWEEN URANYL-NITRATE AND BENZO-15-CROWN-5 - STRUCTURES OF THE (2/1) AND (1/1) COMPLEXES OF BENZO-15-CROWN-5 DIAQUADINITRATODIOXOURANIUM(VI) [J].

DESHAYES, L ;

KELLER, N ;

LANCE, M ;

NIERLICH, M ;

VIGNER, D .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :16-19

[5]

DESHAYES L, 1993, UNPUB POLYHEDRON

[6]

FAIR CK, 1990, MOLEN INTERACTIVE IN

[7] ANHYDROUS URANYL CROWN-ETHER COMPLEXES - H-1 NUCLEAR MAGNETIC-RESONANCE AND X-RAY STUDY [J].

FOLCHER, G ;

CHARPIN, P ;

COSTES, RM ;

KELLER, N ;

VILLARDI, GCD .

INORGANICA CHIMICA ACTA, 1979, 34 (01) :87-90

[8]

FUX P, 1984, J CHIM PHYS PCB, V81, P321, DOI 10.1051/jcp/1984810321

[9] ON THE SOLID-STATE CONFORMATIONS OF 18-CROWN-6 COMPLEXES [J].

FYLES, TM ;

GANDOUR, RD .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1992, 12 (1-4) :313-332

[10] X-RAY STRUCTURAL-ANALYSIS OF DIAQUADINITRATODIOXOURANIUM (VI) 1,4,7,10,13-PENTAOXACYCLOPENTADECANF [U(NO3)2O2(C10H20O5)(H2O)2] [J].

GUTBERLET, T ;

DREISSIG, W ;

LUGER, P ;

BECHTHOLD, HC ;

MAUNG, R ;

KNOCHEL, A .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :1146-1149