REGIOSELECTIVITY IN THE ADDITION OF CARBON NUCLEOPHILES TO 1-FLUORO AND 1,1-DIFLUORO PI-ALLYLPALLADIUM COMPLEXES

被引：51

作者：

SHI, GQ

HUANG, XH

ZHANG, FJ

机构：

[1] Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academia Sinica, 200032 Shanghai

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 35期

关键词：

D O I：

10.1016/0040-4039(95)01278-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Attack on 1-fluoro and 1,1-difluoro pi-allylpalladium complexes by stabilized carbon nucleophiles occurs preferentially at the nonfluorinated terminus, wheras the attack of a nonstabilized carbon nucleophile takes place at the fluorinated end.

引用

页码：6305 / 6308

页数：4

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