SYNTHESIS, STRUCTURE, AND REARRANGEMENT OF 1,3-DIBORA[5]RADIALENES

被引：13

作者：

ENDERS, M

KRAMER, A

PRITZKOW, H

SIEBERT, W

机构：

[1] Anorganisch-Chemisches Institut, Universität Heidelberg, W-6900

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1002/anie.199100841

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new 1,3-bis(dimethylamino) derivative 1 is isoelectronic with decamethyl[5]radialene. The analogous 1,3-dimethyl compound 2 undergoes slow 1,5-sigmatropic H shift to give a 1,3-diborafulvene. This process is faster in the reaction with [Mo(CO)6], whereby the product is the [Mo(CO)4] complex 3.

引用

页码：84 / 85

页数：2

共 9 条

[1]

IYODA M, 1986, J CHEM SOC CHEM COMM, P1794

[2] A NEW APPROACH TO THE CONSTRUCTION OF RADIALENES BY THE NICKEL-CATALYZED CYCLOOLIGOMERIZATION OF [3]CUMULENES (BUTATRIENES) [J].