STRUCTURE OF ADSORPTION CENTERS ON A CARBOSIL SURFACE DEDUCED FROM H-1 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY DATA OF ADSORBED BENZENE AND WATER-MOLECULES

被引：25

作者：

TUROV, VV ^{[1
]}

LEBODA, R ^{[1
]}

BOGILLO, VI ^{[1
]}

SKUBISZEWSKAZIEBA, J ^{[1
]}

机构：

[1] MARIE CURIE SKLODOWSKA UNIV,FAC CHEM,PL-20031 LUBLIN,POLAND

来源：

LANGMUIR | 1995年 / 11卷 / 03期

关键词：

D O I：

10.1021/la00003a041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of benzene and water adsorption complexes on a complex carbon-silica adsorbent (carbosil) surface was studied by H-1 NMR spectroscopy. The adsorbent was obtained by pyrolysis of CH2Cl2 at 500 degrees C on the surface of pyrogeneous silica (Aerosil-300). Disordered fragments of graphite planes were found to be adsorption centers for benzene molecules. Water molecules are sorbed on the residual hydroxyl groups of silica as well as at oxygen-containing adsorption centers of the carbon material. The thicknesses of the solvation shells of benzene and water of initial aerosil and carbon black particles were determined.

引用

页码：931 / 935

页数：5

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