ROTATIONALLY RESOLVED ZERO KINETIC-ENERGY PHOTOELECTRON-SPECTROSCOPY OF NITRIC-OXIDE

被引：44

作者：

REISER, G ^{[1
]}

MULLERDETHLEFS, K ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST PHYS & THEORET CHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 01期

关键词：

D O I：

10.1021/j100180a004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report new ZEKE (zero kinetic energy) photoelectron measurements with rotational resolution for 1 + 1' photoionization through the A(2)SIGMA+ state of nitric oxide. Total angular momentum quantum numbers between 0 and 8 in the intermediate state are selected by different A(2)SIGMA+ <-- X(2)PI(1/2) transitions. Results for different polarizations are also reported. The results of relative ZEKE photoelectron intensities indicate a contribution from the coupling of Rydberg states of different rotational quantum number of the ionic core, and alignment effects.

引用

页码：9 / 12

页数：4

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