(S)-ALPHA-METHOXYPHENYL ACETIC-ACID - A NEW NMR CHIRAL SHIFT-REAGENT FOR THE STEREOCHEMICAL ANALYSIS OF SULFOXIDES

被引：55

作者：

BUIST, PH ^{[1
]}

MARECAK, D ^{[1
]}

HOLLAND, HL ^{[1
]}

BROWN, FM ^{[1
]}

机构：

[1] BROCK UNIV,DEPT CHEM,ST CATHARINES,ON L2S 3A1,CANADA

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0957-4166(94)00337-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of (S)-alpha-methoxyphenyl acetic acid (MPAA) as a general chiral H-1 NMR shift reagent for the stereochemical analysis of sulfoxides is demonstrated. Using this methodology, both the enantiomeric purity and the absolute configuration of a wide variety of sulfoxides can be determined.

引用

页码：7 / 10

页数：4

共 10 条

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