REDOX STATE OF IRON AND ITS RELATED EFFECTS IN THE CAO-P2O5-FE2O3 GLASSES

被引：52

作者：

KUMAR, B ^{[1
]}

LIN, S ^{[1
]}

机构：

[1] ZIMMER INC,WARSAW,IN 46580

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1991年 / 74卷 / 01期

关键词：

dissolution; Glass; iron; oxygen; reduction–oxidation;

D O I：

10.1111/j.1151-2916.1991.tb07322.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Iron exists in Fe2+ and Fe3+ states in CaO-P2O5-Fe2O3 glasses and they impart characteristic optical absorption bands that allow analysis of relative proportion of the two species. This communication reports the redox states of glasses melted under air, argon, and oxygen atmospheres and relates them to the dissolution rates. The dissolution rate was found to be related to the redox state and it is lowered if the glass is melted under oxidizing atmospheres.

引用

页码：226 / 228

页数：3

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