THE ROLE OF AN ALUMINUM-TERTIARY ALKANOLAMINE CHELATE IN THE SYNTHESIS OF LARGE CRYSTAL ZEOLITE NAA

被引：22

作者：

MORRIS, M ^{[1
]}

SACCO, A ^{[1
]}

DIXON, AG ^{[1
]}

THOMPSON, RW ^{[1
]}

机构：

[1] WORCESTER POLYTECH INST, DEPT CHEM ENGN, WORCESTER, MA 01609 USA

来源：

ZEOLITES | 1991年 / 11卷 / 02期

关键词：

ZEOLITE CRYSTALLIZATION; ALUMINUM-ALKANOLAMINE CHELATE; ZEOLITE NAA;

D O I：

10.1016/0144-2449(91)80413-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The role of 2, 2', 2"-nitrilotriethanol (triethanolamine, TEA) as a solution additive in the synthesis of large crystal zeolite NaA has been determined by a combination of Al-27 n.m.r. and zeolite syntheses using related compounds as solution additives. TEA was found to chelate aluminum, with its hydroxyl groups being directly involved in bonding to the metal ion. In addition, it was found that four additional tertiary alkanolamines to TEA were effective as solution additives in allowing the synthesis of large crystal zeolite NaA.

引用

页码：178 / 183

页数：6

共 23 条

[1] AL-27 NUCLEAR MAGNETIC-RESONANCE STUDIES OF HYDROLYSIS AND POLYMERIZATION OF HEXA-AQUO-ALUMINUM(III) CATION [J].

AKITT, JW ;

LESTER, GD ;

KHANDELWAL, BL ;

GREENWOOD, NN .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (05) :604-+

[2] SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAMETHYLAMMONIUM GISMONDINE [J].

BAERLOCHER, C ;

MEIER, WM .

HELVETICA CHIMICA ACTA, 1970, 53 (06) :1285-+

[3]

BARRER RM, 1982, HYDROTHERMAL CHEM ZE, P157

[4]

BARRER RM, 1966, J CHEM SOC, P971

[5]

BURCHART ED, 1989, ZEOLITES, V9, P432

[6] GEL GROWTH OF LARGE CRYSTALS OF SODIUM A AND SODIUM X ZEOLITES [J].

CHARNELL, JF .

JOURNAL OF CRYSTAL GROWTH, 1971, 8 (03) :291-&

[7]

DIANXU NW, 1986, FOR LANG ED, V31, P820

[8]

HARRIS RK, 1983, NUCL MAGN RESON, P118

[9]

HARVEY G, 1989, ACS SYM SER, V398, P49

[10]

KERR GT, 1966, INORG CHEM, V5, P1537, DOI 10.1021/ic50043a015

← 1 2 3 →