HIGH-RESOLUTION CHROMATOGRAPHIC CHARACTERIZATION OF DEPOLYMERIZED COALS OF DIFFERENT RANK - ALIPHATIC AND AROMATIC-HYDROCARBONS

A selective, low temperature depolymerization procedure has been applied to four coals of different rank to obtain products that are representative of the original structural units (monoclusters) of the coal macromolecular component, and that are amenable to chromatographic analysis. The monocluster products of this depolymerization procedure retain most of their original aromatic-hydroaromatic structures, whereas functional groups serving as intercluster linkages, e.g. alkylene and etheric groups, undergo predictable modification. A comparison of liquid C-13 n.m.r. spectra of the products and solid state C-13 n.m.r. spectra of the original coals showed only minor changes in the aromaticities between the solid and depolymerized products, but some loss of carbonyl carbons was detected in all of the coals. Both the tetrahydrofuran pre-extract and the depolymerized products of the four coals were separated into chemical classes by adsorption chromatography. Two of these fractions were found to consist predominantly of aliphatic hydrocarbons (paraffins and naphthenes) and alkylsubstituted bi-, tri- and (some) tetracyclic arenes. The fractions were analysed using gas chromatography-mass spectrometry. Structural identifications were based on a combination of chromatographic retention and mass spectral fragmentation data. For the lower rank coals, the compositions of the pre-extracts were quite different from the corresponding depolymerized coal products, and contained various molecular biological markers. The compositions of the pre-extracts became closer to those of the depolymerized coal products as rank increased.