PHOTOADDITION OF KETENE SILYL ACETALS TO ELECTRON-DEFICIENT ARYLALKENES VIA SINGLE-ELECTRON TRANSFER

被引：13

作者：

MIZUNO, K

TAKAHASHI, N

NISHIYAMA, T

INOUE, H

机构：

[1] Department of Applied Chemistry, College of Engineering, University of Osaka Prefecture, Sakai, Osaka

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 41期

关键词：

D O I：

10.1016/0040-4039(95)01543-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photoreaction of 1-cyano-2-phenylethene and 1,1-dicyano-2-phenylethene with beta,beta-dialkyl-substituted ketene silyl acetals in acetonitrile in the presence of aromatic hydrocarbon as a photosensitizer regioselectively afforded alkylated products in high yields.

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页码：7463 / 7466

页数：4

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