THE FIRST DINUCLEAR LOW-VALENT SAMARIUM COMPLEX WITH A SHORT SM-SM CONTACT

被引：37

作者：

SONG, JI ^{[1
]}

GAMBAROTTA, S ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 19期

关键词：

COMPLEXES WITH MACROCYCLIC LIGANDS; METAL-METAL INTERACTIONS; PORPHYRINOIDS; SAMARIUM COMPOUNDS;

D O I：

10.1002/anie.199521411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transamination of the amidosamarium complex [{(Me3Si)2N}2Sm(tmeda)] with octaethylporphyrinogen (OEPG‐H4) gives the dinuclear complex [(OEPG)Sm2(Et2O)2], which has two SmII centers and a short Sm–Sm contact. (In the structure shown on the right the Et2O ligands are omitted for clarity.) (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2141 / 2143

页数：3

共 52 条

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