THE FIRST DINUCLEAR LOW-VALENT SAMARIUM COMPLEX WITH A SHORT SM-SM CONTACT

被引:37
作者
SONG, JI [1 ]
GAMBAROTTA, S [1 ]
机构
[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 19期
关键词
COMPLEXES WITH MACROCYCLIC LIGANDS; METAL-METAL INTERACTIONS; PORPHYRINOIDS; SAMARIUM COMPOUNDS;
D O I
10.1002/anie.199521411
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transamination of the amidosamarium complex [{(Me3Si)2N}2Sm(tmeda)] with octaethylporphyrinogen (OEPG‐H4) gives the dinuclear complex [(OEPG)Sm2(Et2O)2], which has two SmII centers and a short Sm–Sm contact. (In the structure shown on the right the Et2O ligands are omitted for clarity.) (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码:2141 / 2143
页数:3
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