SYNTHESIS OF MONOPROTECTED 2-ALKYLIDENE-1,3-PROPANEDIOLS BY AN UNUSUAL SN2' MITSUNOBU REACTION

被引：36

作者：

CHARETTE, AB

COTE, B

机构：

[1] Département de chimie, Université de Montréal, Montréal

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)91807-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and efficient route to monoprotected E- and Z-2-alkylidene-1,3-propanediols was developed. The key step involves an unusual regio- and stereoselective SN2' Mitsunobu reaction of substituted 3-hydroxy-2-methylenealkenoate.

引用

页码：6833 / 6836

页数：4

共 21 条

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