SOLVENT EFFECTS ON BASICITY OF STERICALLY HINDERED PYRIDINES

被引：29

作者：

MCDANIEL, DH

OZCAN, M

机构：

[1] Department of Chemistry, University of Cincinnati, Cincinnati

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 05期

关键词：

D O I：

10.1021/jo01269a046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The pKavalues of pyridine, 2-t-butylpyridine, and 2,6-di-t-butylpyridine have been measured in aqueous solutions of methanol, ethanol, and 2-propanol at concentrations of alcohol ranging up to 70 vol %. The data support the conclusion that the base weakening effect of the alkyl groups in 2,6-di-t-butylpyridine is due to steric inhibition of solvation. © 1968, American Chemical Society. All rights reserved.

引用

页码：1922 / &

共 10 条

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