STUDY OF URANYL(VI) ION REDUCTION AT VARIOUS IONIC STRENGTHS OF SODIUM-PERCHLORATE

被引：10

作者：

DJOGIC, R

BRANICA, M

机构：

[1] Centre for Marine Research Zagreb, Rudjer Bošković Institute, 41001 Zagreb

来源：

ANALYTICA CHIMICA ACTA | 1993年 / 281卷 / 02期

关键词：

VOLTAMMETRY; URANYL(VI);

D O I：

10.1016/0003-2670(93)85184-L

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

To determine the number of water molecules involved in the electrode reaction of the uranyl(VI)-(V) redox pair, square-wave voltammetric measurements of uranyl(VI) ion reduction in non-complexing NaClO4 media at pH 2 and different ionic strengths between 0.1 and 8.5 mol l-1 were performed. The available literature water activity data were compared and taken into account. The loss of two water molecules was established.

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页码：291 / 297

页数：7

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